Using IR vibrations to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C–H functionalization† †Electronic supplementary information (ESI) available: Experimental procedures, tabulated descriptors, and model development MATLAB commands. See DOI: 10.1039/c5sc00357a

Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant† †Electronic supplementary information (ESI) available: Data for new compounds and experimental procedures. CCDC 1042327. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03350g

Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams† †Electronic supplementary information (ESI) available: Data for new compounds and experimental procedures and theoretical studies on mechanisms. CCDC 979559 and 990983. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00092k Click here for additional data file. Click here for additional data file.

Laboratory of Molecular Recognition an Zhejiang University, Hangzhou 310027, Zh ac.cn State Key Laboratory of Organometallic C Chemistry, Chinese Academy of Sciences, [email protected] Shanghai Key Laboratory of Magnetic Reson Normal University, Shanghai 200062, P. R. † Electronic supplementary information ( and experimental procedures and theor 979559 and 990983. For ESI and crystallo format s...

Copper-catalyzed intermolecular C(sp3)–H bond functionalization towards the synthesis of tertiary carbamates† †Dedicated to Professor Iwao Ojima on his 70th birthday. ‡ ‡Electronic supplementary information (ESI) available: Experimental procedures, characterization data, and 1H and 13C NMR charts. See DOI: 10.1039/c5sc00238a

Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones† †Electronic supplementary information (ESI) available: Experimental procedures and compound characterization. CCDC 1021286. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02590c Click here for additional data file. Click here for additional data file.

We report the regioselective synthesis of dihydroisoquinolones from aliphatic alkenes and O-pivaloyl benzhydroxamic acids mediated by a Rh(III) precatalyst bearing sterically bulky substituents. While the prototypical Cp* ligand provides product with low selectivity, sterically bulky Cpt affords product with excellent regioselectivity for a range of benzhydroxamic acids and alkenes. Crystallogr...

A DFT calculation-inspired Rh(i)-catalyzed reaction via suppression of α-H shift in α-alkyldiazoacetates† †Electronic supplementary information (ESI) available: DFT calculation details, optimized structures, experimental data and biological activity tests. CCDC 984118. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00257b Click here for additional data file. Click here for additional data file.

Shanghai Engineering Research Center of Development, East China Normal Univers [email protected]; [email protected] School of Chemistry and Chemical Eng 530004, China NYU-ECNU Center for Computational C 200062, China † Electronic supplementary information ( optimized structures, experimental data 984118. For ESI and crystallographic data DOI: 10.1039/c7sc00257b ‡ These authors contributed equ...